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CHM1022 - Chemistry II - S2 2025

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The order of the increasing stability for the Platinum (Pt) complexes is: 

 (ethylenediamine = en)                 

(triethylenetetramine = trien)

a) [Pt(trien)]2+ < [Pt(en)2]2+ < [Pt(NH3)4]2+  

b) [Pt(NH3)4]2+ < [Pt(trien)]2+ < [Pt(en)2]2+ 

c) [Pt(en)2]2+ < [Pt(trien)]2+< [Pt(NH3)4]2+ 

d) None of the options is correct.

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The following ligand given below has a denticity of

a) 4 

b) 2

c) 3 

d) none of the options are correct.

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In the complex  [Ni(EDTA)]2-, the oxidation state and coordination number of Ni are:

EDTA (ethylenediamine tetraacetic acid)=  

a) +2, 4

b) +2, 6

c) +3, 4

d) +3, 6

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How many ions will the following complex [Co(NH3)5(NO2)](NO2)2 give when dissolved in water?

a) 1

b) 2

c) 3

d) 4

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The electronic configuration of Zn in the complex [ZnCl4]2- is    

a) [Ar]3d10

b) [Ar]4s23d10

c) [Ar]4s23d8

d) none of the options are correct.

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The acidity of hexaaqua ions follows which trend?

A) [Fe(OH₂)₆]²⁺ < [Fe(OH₂)₆]³⁺

B) [Fe(OH₂)₆]³⁺ < [Fe(OH₂)₆]²⁺

C) Both are equally acidic

D) None of these options are right

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Which of the following compounds is not a linkage isomer?

a) Hg[Co(SCN)4]

b) [Cr(H2O)5(NO2)]Cl2

c) [CoCl2(en)2]Cl

d) K[Cr(NH3)2(ONO)4]

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 Identify the correct naming for [Zn(OH)4]2-.

a) Zinc tetrahydroxide

b) Tetrahydroxozincate(II)

c) Tetrahydroxidozincate(II)

d) Tetrahydroxylzincate(II)

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