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CH224[A] — Inorganic Chemistry: Co-Ordination Chemistry and S-Block Groups (2025-26:Semester 2)

CH224[A] — Inorganic Chemistry: Co-Ordination Chemistry and S-Block Groups (2025-26:Semester 2)

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Consider the coordination complex below. What is its IUPAC name? Note: Isomerism is not considered.

Triamminediaqua(thiocyanato-κS)molybdenum(II)

❌

Triamminediaqua(thiocyanato-κN)molybdenum(II)

✅

Triamminediaqua(thiocyanato-κN)molybdate(II)

❌

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Consider the coordination complex below. What is its IUPAC name? Note: Isomerism is not considered.

μ-hydroxido-bis(triamminedichloridoiridium(IV))

✅

μ₃-hydroxido-bis(triamminedichloridoiridium(IV))

❌

κ-hydroxido-bis(triamminedichloridoiridium(IV))

❌

μ-hydroxido-bis(triamminedichloridoiridium(III))

❌

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Consider the coordination complex below. What is its IUPAC name? Note: Isomerism is not considered.

Tris(ethylenediamine)cobalt(III)

✅

Tri(ethylenediamine)cobalt(III)

❌

Tri(ethylenediamine)cobalate(III)

❌

Tris(ethylenediamine)cobalt(II)

❌

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Consider the coordination complex below. What is its IUPAC name? Note: Isomerism is not considered.

Dichloridodiaqua(oxalato)ruthenate(II)

❌

Oxalatodiaquabis(chloride)ruthenium(II)

❌

Diaquadichlorido(oxalato)ruthenate(II)

✅

Diaquadichlorido(oxalato)ruthenium(II)

❌

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Consider the coordination complex below. What is its IUPAC name? Note: Isomerism is not considered.

Triamminetriaquairon(II)

✅

Triamminetriaquairon(III)

❌

Triaquatriammineiron(III)

❌

Triaquatriammineiron(II)

❌

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Consider the following IUPAC coordination complex name. Determine what metal is at the centre of the complex and whether the complex possesses a negative charge or is positive/neutral?

Potassium diaquabis(oxalato)manganate(III)

Magnesium and complex is negatively charged.

❌

Manganate and complex is positively charged/neutral.

❌

Manganese and complex is positively charged/neutral.

❌

Manganese and complex is negatively charged.

✅

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Consider the coordination complex below. What notation is used to describe the bridge and bridging ligand?