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CHEM1832-Chemistry for Health Science (T1 2025)

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The reaction A  arrow  B is first order with respect to [A]. Consider the following data:

 

 Time (s)0.05.010.015.020.0
 [A] (M)0.200.140.100.0710.050

 

The rate constant for this reaction is ________ s–1

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The kinetics of the reaction below were studied and it was determined that the reaction rate did not change when the concentration of B was tripled. The reaction is ________ order with respect to B

A  +  B  arrow  P

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Kinetic data was recorded for a chemical reaction and the graphs below were were produced using the data. Based on these graphs, determine the overall order of the rate law for this reaction.

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Which of the expressions below is the differential rate law for a first order reaction?

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Nitrosyl bromide decomposes according to the following equation:

2NOBr (g) ⇌ 2NO (g) + Br2 (g) 

A sample of NOBr (0.798 mol) was placed in an empty 1.00 L flask. At equilibrium the flask contained 0.188 mol of NOBr. How many moles of Br2 are in the flask at equilibrium?

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Consider the following endothermic reaction at equilibrium:

2NH3 (g) ⇌ N2 (g) + 3H2 (g)            ΔH° = +92.4 kJ/mol

Le Châtelier's principle predicts that adding N2 (g) to the system at equilibrium will result in ________.

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Nitrosyl bromide decomposes according to the following equation:

2NOBr (g) ⇌ 2NO (g) + Br2 (g) 

A sample of NOBr (0.66 mol) was placed in an empty 1.00 L flask. At equilibrium the flask contained 0.163 mol of NOBr. How many moles of NO are in the flask at equilibrium?

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For the reaction graph below, which letter corresponds to the reaction at chemical equilibrium?

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Consider the following sketch of the interaction energy for two atoms as a function of distance between the atoms.

Which label, a) to e) points to the region where nuclei-nuclei repulsion is dominating the interaction energy?

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How many 4p orbitals exist?

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