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Chemistry / Chemie - 144

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Which of the following combinations (where all weak components are in excess) can be used to produce a buffer solution?Watter van die volgende kombinasies (waar alle swak komponente in oormaat is) kan gebruik word om 'n bufferoplossing te lewer?
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A chemist decides to prepare a buffer by adding 10.0 mL of 0.560 M NaOH to 50.0 mL of 0.140 M HClO. What is the pH of this buffer? 

(Ka(HClO) = 3.0 x 10-8)

(Please provide your answer rounded off to 2 decimal places.)

'n Chemikus besluit om 'n buffer voor te berei deur 10.0 mL van 0.560 M NaOH by 50.0 mL van 0.140 M HClO te voeg. Wat is die pH van hierdie buffer?

(Ka(HClO) = 3.0 x 10-8)

(Gee asb jou antwoord afgerond tot 2 desimale plekke.)

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The Ka of hypochlorous acid (HClO) is 3.0 x 10-8 at 25 °C. What is the pH of a 0.015 M aqueous solution of HClO at 25 °C?

(Please provide your answer rounded off to 2 decimal places.)

Die Ka van hipochlorigsuur (HClO) is 3.0 x 10-8 by 25 °C. Wat is die pH van 'n 0.015 M waterige oplossing van HClO by 25 °C?

(Gee asb jou antwoord afgerond tot 2 desimale plekke.)

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What is the pH of a buffer solution consisting of 1.00 g of HClO (Mr = 52.460 g.mol-1) and 1.00 g of NaClO (Mr = 74.442 g.mol-1) in a 1.00 L flask?

(Ka(HClO) = 3.0 x 10-8)

Please give your answer rounded off to 2 decimal places.

Wat is die pH van 'n buffer oplossing wat bestaan uit 1.00 g HClO (Mr = 52.460 g.mol-1) en 1.00 g NaClO (Mr = 74.442 g.mol-1) in 'n 1.00 L fles? 

(Ka(HClO) = 3.0 x 10-8)

Gee asb jou antwoord afgerond tot 2 desimale plekke. 

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In step 4 of the diazepam synthesis, a methylation reaction takes place. A proposed mechanism is shown below. Study it and comment on any errors that you think have been shown.In stap 4 van die diazepam-sintese vind 'n metieleringsreaksie plaas. 'n Voorgestelde meganisme word hieronder getoon. Bestudeer dit en lewer kommentaar op die foute wat jy sien. 
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Suggest a method (i.e. a sequence of steps) that you would take in order to achieve step 1 of the synthesis of diazepam. You must:

  1. start with bromobenzene and,
  2. add any other reagents you feel necessary in order to make the ketone product.

Stel 'n metode voor (dit wil sê 'n reeks stappe) wat jy sal neem om stap 1 van die sintese van diazepam te bereik. Jy moet:

  1. met brombenzeen begin en,
  2. enige ander reagense byvoeg wat jy nodig het om die ketoonproduk te maak.
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A Vitamin C (ascorbic acid) tablet, with a mass of 5.137 g, was completely dissolved in water and made to volume in a 100 mL volumetric flask. A 0.0103 M NaOH solution was used to titrate against this ascorbic acid (C6H8O6) solution. The average (Volume NaOH/Volume C6H8O6) i.e. (Vb/Va) ratio at the endpoint was determined as 11.67.

Determine the mass percentage of ascorbic acid  in the original tablet. (Mr of ascorbic acid = 176.12 g/mol)

The balanced reaction equation is given below. Please provide your answer rounded off to two decimal figures.

'n Vitamien C (askorbiensuur) tablet, met 'n massa van 5.137 g, is volledig in water opgelos en in 'n volumetriese fles opgemaak tot 'n volume van 100 mL. 'n 0.0103 M NaOH oplossing is gebruik om teen hierdie askorbiensuur (C6H8O6) oplossing te titreer. Die gemiddelde (Volume NaOH/Volume C6H8O6) d.w.s. (Vb/Va) verhouding by die endpunt is vasgestel as 11.67.

Bepaal die massapersentasie askorbiensuur in die oorspronklike tablet. (Mr askorbiensuur = 176.12 g/mol)

Die gebalanseerde reaksievergelyking word hieronder gegee. Gee asseblief jou antwoord afgerond tot twee desimale syfers.

C6H8O6 (aq) + NaOH (aq) → C6H7O6Na (aq) + H2O (ℓ)

 

 

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Identify the strong acids.Identifiseer die sterk sure.
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A 100.0 mL sample of acetic acid requires 100.0 mL of 0.100 M NaOH to reach the phenolphthalein end point (equivalence point) during a titration. What is the concentration of the conjugate base formed at the end point?'n 100.0 mL Monster van asynsuur benodig 100.0 mL van 0.100 M NaOH om die fenolftaleïen endpunt (ekwivalensiepunt) te bereik tydens ‘n titrasie. Wat is die konsentrasie van die gekonjugeerde basis wat gevorm het by die endpunt
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Consider the pH titration between 50.0 mL 0.200 M acetic acid (Ka = 1.8 x 10-5, pKa = 4.74), and 100.0 mL of 0.100 M NaOH. 

What is the pOH of the solution at the endpoint?

(Please give your answer rounded off to 2 decimal places.)

Oorweeg die pH-titrasie tussen 50.0 mL 0.200 M asynsuur (Ka = 1.8 x 10-5, pKa = 4.74) en 100.0 mL van 0.100 M NaOH.

Wat is die pOH van die oplossing by die endpunt?

(Gee asb jou antwoord afgerond tot 2 desimale plekke.)

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