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25℃, 1気圧(101.3 kPa)で二酸化炭素(CO 2 )は純水1.0 dm 3 に0.029 mol 溶解する。この水溶液のpHを小数点以下1桁まで答え...

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25℃, 1気圧(101.3 kPa)で二酸化炭素(CO2)は純水1.0 dm3に0.029 mol 溶解する。この水溶液のpHを小数点以下1桁まで答えなさい。なお炭酸(H2CO3)は二段階に解離(K= 4.3×10-7、K= 5.6 × 10-11)し、HCO3-, CO32- を与えるが、CO32- は非常に微量であるので無視してよい。なお溶液の活量定数は1.0としてよい。

 Carbon dioxide (0.029 mol) dissolves in water at 25℃ under 101.3 kPa. Carbon dioxide connects with water to give H2CO3. H2CO3 dissociates to give HCO3- and CO32-. However, CO32- is very trace, therefore you may ignore formation of CO32-. Answer the pH of this solution  to the first decimal place.

 

 

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