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CHEM1011-CHEM1031-CHEM1051-Chemistry 1A (T1 2025)

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Consider the following statements:

(i)A reduction half equation contains at least one species that is being reduced and at least one electron on the left hand side of the reaction arrow.
(ii)A redox reaction in an electrochemical cell involves electron transfer between two species where electrons travel between two electrodes via an external electrical circuit.
(iii)A redox reaction where all species are in direct contact with one another does not involve electron transfer.
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The reaction below is exothermic:

2SO2 (g) + O2 (g) ⇌ 2SO3 (g)

Le Châtelier's Principle predicts that ________ will result in an increase in the number of moles of SO3 (g) in the reaction container.

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Consider the reaction below, for which K = 7.26 × 10–2 at 450.0 °C. 

2Cl2 (g) + 2H2O (g) ⇌ 4HCl (g) + O2 (g)

What is the value of K at this temperature for the following reaction?

Cl2 (g) + H2O (g) ⇌ 2HCl (g) + ½O2 (g)

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Consider the following equilibrium reaction:

H2CO3 (aq)  ⇌  H+ (aq) + HCO3 (aq);     K = 5.0 x 10–7

 If the initial concentrations of the species are:

[H2CO3] = 0.12 M;   [H+] = 5.00 x 10–5 M;   [HCO3] = 4.00 x 10–3 M

Which one of the statements below describes the relationship between Q and K and then the correct direction of chemical change?

 

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A galvanic cell was constructed where one electrode was a Cu2+(aq)|Cu(s) electrode and the other was an M2+(aq)|M(s) electrode. The potential difference between the two electrodes was measured to be 1.03 V with the M2+(aq)|M(s) electrode being the more positive electrode. What is the potential of the M2+(aq)|M(s) electrode with respect to the standard hydrogen electrode?

Data: E°(Cu2+(aq)|Cu(s)) = +0.34 V

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Which of these cell diagrams correctly represents a cell in which this reaction is happening?

Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s)

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A galvanic cell constructed using an X+|X electrode connected to a standard copper half–cell (as used in this experiment) was found to have a cell potential of 0.45 V with the X+|X electrode being positive with respect to the copper electrode. Where on the number line below would you place the X+|X electrode?

representation of half-cell potentials on a number line

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A galvanic cell was constructed where one electrode was a Cu2+(aq)|Cu(s) electrode and the other was an M2+(aq)|M(s) electrode. The potential difference between the two electrodes was measured to be 0.27 V with the copper electrode being the more positive electrode. What is the potential of the M2+(aq)|M(s) electrode with respect to the standard hydrogen electrode?

Data: E°(Cu2+(aq)|Cu(s)) = +0.34 V

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Consider an iron nail with silver wrapped onto it, immersed in an agar gel containing phenolphthalein and potassium ferricyanide. After a few minutes a pink colour appeared in the gel around the silver metal and a blue colour was observed in the gel near the tip and head of the iron nail. What is the most accurate interpretation of these observations?

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A galvanic cell constructed using an X+|X electrode connected to a standard copper half–cell (as used in this experiment) was found to have a cell potential of 0.45 V with the X+|X electrode being negative with respect to the copper electrode. Where on the number line below would you place the X+|X electrode?

representation of half-cell potentials on a number line

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