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MATS1101 - Engineering Materials and Chemistry - T3 2025

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How do you measure the 5 mL of 2 M nitric acid which is added to the 100 mL volumetric flask in step 3?

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The concentration of Fe3+ in the stock haematite solution is large and if it were mixed with KSCN the light absorbance would be too large to accurately measure. How is this problem avoided in the method for this experiment?

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10.0 mL of a solution of Fe3+ was placed in a 100 mL volumetric flask. 5mL of nitric acid and 5 mL of KSCN solution were added. Water was added to make the solution up to the mark on the neck of the volumetric flask, and the solution was thoroughly mixed. The concentration of the solution in the volumetric flask was determined to be 0.00222 mol/L by spectrophotometry. What was the concentration of the original Fe3+ solution?

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What are the quantities plotted on the calibration graph for the spectrophotometry experiment you will be doing?
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The graph below is a calibration curve for determining the concentration of Cu2+ from light absorbance at a wavelength of 610 nm. This calibration curve was created in the same way as the one involving Fe2+ you will generate in this experiment.

If solution of copper has an absorbance of 0.901 at 610 nm, what was the concentration Cu2+ in the solution?

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The part shown in the figure below is to be used as a rotating member in a machine. Which of the following will NOT increase the fatigue life of this part?

a rotating member in a machine

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A structural component is to be made from 4340 steel in the form of a very wide plate. The steel has a yield strength of 1500 MPa and a plane strain fracture toughness of 60 MPa m1/2. Assume plane strain conditions exist. It is not possible to detect flaw sizes less than a=3mm (resolution limit of flaw detection apparatus). Determine whether or not a critical flaw is subject to detection. Assume that the design stress level (i.e., the maximum stress to which the component will be loaded in service) is half the yield strength and that Y is 1.0.
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The part shown in the figure below is to be used as a rotating member in a machine. Which of the following will NOT increase the fatigue life of this part?

a rotating member in a machine

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The part shown in the figure below is to be used as a rotating member in a machine. Which of the following will NOT increase the fatigue life of this part?

a rotating member in a machine

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An aircraft wing component made from an aluminium alloy fractures at a stress of 300 MPa when the maximum internal crack is of length 2a=2.0 mm. For the same component, made from the same alloy in the same condition (i.e., with the same fracture toughness), determine the stress level at which fracture will occur with a critical internal crack of length 2a=3.0 mm. Assume that Y=1.
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