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CHEM1011-CHEM1031-CHEM1051-Chemistry 1A (T1 2025)

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A galvanic cell was constructed where one electrode was a Cu2+(aq)|Cu(s) electrode and the other was an M2+(aq)|M(s) electrode. The potential difference between the two electrodes was measured to be 1.03 V with the M2+(aq)|M(s) electrode being the more positive electrode. What is the potential of the M2+(aq)|M(s) electrode with respect to the standard hydrogen electrode?

Data: E°(Cu2+(aq)|Cu(s)) = +0.34 V

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A galvanic cell constructed using an X+|X electrode connected to a standard copper half–cell (as used in this experiment) was found to have a cell potential of 0.45 V with the X+|X electrode being positive with respect to the copper electrode. Where on the number line below would you place the X+|X electrode?

representation of half-cell potentials on a number line

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Which of these cell diagrams correctly represents a cell in which this reaction is happening?

Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s)

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Consider an iron nail with silver wrapped onto it, immersed in an agar gel containing phenolphthalein and potassium ferricyanide. After a few minutes a pink colour appeared in the gel around the silver metal and a blue colour was observed in the gel near the tip and head of the iron nail. What is the most accurate interpretation of these observations?

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A galvanic cell constructed using an X+|X electrode connected to a standard copper half–cell (as used in this experiment) was found to have a cell potential of 0.45 V with the X+|X electrode being negative with respect to the copper electrode. Where on the number line below would you place the X+|X electrode?

representation of half-cell potentials on a number line

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A galvanic cell was constructed where one electrode was a Cu2+(aq)|Cu(s) electrode and the other was an M2+(aq)|M(s) electrode. The potential difference between the two electrodes was measured to be 0.27 V with the copper electrode being the more positive electrode. What is the potential of the M2+(aq)|M(s) electrode with respect to the standard hydrogen electrode?

Data: E°(Cu2+(aq)|Cu(s)) = +0.34 V

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Consider an iron nail with magnesium wrapped onto it, immersed in an agar gel containing phenolphthalein and potassium ferricyanide. After a few minutes a pink colour appeared in the gel around the iron nail and but no blue colour was observed in the gel. What is the most accurate interpretation of these observations?

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In the corrosion experiment you will prepare iron nails which are in good contact with a piece of another metal. How will you do this?

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Which of these most accurately describes how the iron nails will be cleaned in this experiment?

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To avoid burns when preparing the agar solution which of these must be not touched until it has cooled? Only select correct answers, selecting incorrect answers will result in a reduced mark. 

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