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CHEM1011-CHEM1031-CHEM1051-Chemistry 1A (T1 2025)

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Based on the MO diagram of the previous question,

  1. What is the bond order of the O-H bond? [1 mark]

  2. Why do we call OH a radical? [1 mark]
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Which of the scenarios below are examples of cathodic protection?

  1. Using a brass alloy for boat propellors.
  2. Treating exposed steel surfaces with acids such as HF.
  3. Using paints with pigments containing Fe2+ to coat bridges
  4. Attaching the metal to be protected to a power supply, making it an electrode in an electrolytic cell
  5. Galvanizing steel by coating it in a thin layer of zinc.
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At 328 K the vapour pressure of acetone, (CH3)2CO, is 98.9 kPa, and that of chloroform, CHCl3, is 84.4 kPa. What would be the vapour pressure of a solution composed of 100 g of acetone and 113 g of chloroform if it exhibited ideal behaviour (i.e. obeyed Raoult’s Law)? Give your answer in units of kPa (just type in numerical answer)

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Superoxide salts are used to generate oxygen gas on space flights and submarines. Superoxides undergo hydrolysis (a reaction with water) to generate oxygen gas, hydrogen peroxide and potassium hydroxide:

2KO2(s) + 2H2O(g) → 2KOH(s) + H2O2(g) + O2(g)              ΔrxnH° = +64.95 kJ mol–1    reaction 1

The peroxide produced then decomposes to produce water and oxygen:

H2O2(g) → H2O(g) + ½O2(g)                                              ΔrxnH° = –146.9 kJ mol–1     reaction 2

Potassium hydroxide (KOH) reacts with carbon dioxide in the air potassium carbonate and potassium bicarbonate:

2KOH(s) + CO2(s) → K2CO3(s) + H2O(g)                              ΔrxnH° = –146.9 kJ mol–1     reaction 3

KOH(s) + CO2(s) → KHCO3(s)                                              ΔrxnH° = –145.0 kJ mol–1     reaction 4

Using the information given above, calculate the reaction enthalpy for the process below:

4KO2(s) + 4CO2(g) + 2H2O(g) → 4KHCO3(s) + 3O2(g)         ΔrxnH° = ?                           reaction 5

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The Rydberg constant is given by:

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where me is the mass of the electron, e is the charge of the electron, 𝜖0 is the permittivity of free space (a Physics constant), h is Planck’s constant and c is the speed of light in a vacuum. The value of the Rydberg constant in our universe is 1.0973 × 107 m–1. The energy of the 1s orbital in hydrogen  is –2.18 x 10–18 J.

The frequency of a spectral transition for a single-electron atom with nuclear charge Z is given by:

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"Muonic hydrogen" is the same as regular hydrogen, only the electron has been replaced by a muon which has a mass 207 greater than the electron but has the same charge as the electron.

In regular hydrogen the emission for the n1 = 3 to n2 = 2 transition in the Balmer series wavelength of 656.3 nm. In "Muonic Hydrogen,' how would the wavelength for the same transition change compared to regular hydrogen:

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Determine ΔG° for a cell that utilizes the following reaction:

Cl2(g) + 2Br(aq) → 2Cl(aq) + Br2(l)

The standard reduction for the chlorine gas is 1.360 volts and the standard reduction for the bromine liquid is about 1.075 volts.

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